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BILINGUAL
HAZARDOUS MATERIALS
GENERAL AWARENESS TRAINING
MARKING AND LABELING

MARCACIÓN Y ETIQUETAS
The format for the material contained herein was developed using Presentation Task
Force and Corel Draw, WordPerfect, and Presentations.
The editors of this material and the Federal Highway Administration make no
representation as to the accuracy of the Spanish translation contained herein. The
material contained in this presentation is for general information and training
purposes only. To determine specific regulatory requirements, consult the most
current copy of 49 Code of Federal Regulations Parts 100-185.
Los redactores de este material y la Administración Federal de Carreteras no hacen
ninguna representación en cuanto a la exactitud de la traducción Española que se
contenga aqui dentro. El material que está contenido en este folleto es para
propósitos de capacitación solamente. Para requisitos específicos, favor de leer 49
Código de Reglamentos Federales Partes 100-185.
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Marking The Term Marking Means..... |
4: Marking and Labeling.
The term "marking," as used in the HMR, means applying the required information
to the outside of shipping containers. This includes the descriptive name of the
hazardous material plus any required instructions and/or cautions.
MARKING AND LABELING III-2
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Before Offering the Package.. Mark It!
49 CFR 172.300 |
Each person who OFFERS a hazardous material for transportation must mark each
package, freight container and the transport vehicle as prescribed in the HMR.
Additionally, when required, each CARRIER shall mark each package, freight
container and the transport vehicle, as prescribed.
172.300
MARKING AND LABELING III-3
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Basic Marking
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Each person who offers for transportation a hazardous material in a packaging of
119 gallons rated capacity or less must mark the package with:
The proper shipping name, and
The identification number preceded by UN or NA as appropriate.
However, there are exceptions.
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Inhalation Hazard
49 CFR 172.313
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"Inhalation Hazard" must be marked on any package containing material that meets
the criteria of a "Poison-Inhalation Hazard" material. The "inhalation hazard"
marking must appear in association with the label or labels.
Bulk packagings must be marked on two sides.
MARKING AND LABELING III-4
If a package of hazardous waste has the EPA marking shown here, the word
"waste" need not be repeated on the package. Without this EPA marking, the word
"waste" is required to be marked on the package before the proper shipping name. 172.301(a)
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Marking for Hazardous Wastes
49 CFR 172.301(a)
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When packagings contain hazardous materials with N.O.S. proper shipping names,
always check 172.203(k). If listed in 172.203(k), mark both the n.o.s. proper
shipping name and the technical name of the material on the packaging. Put the
technical name in parenthesis in association with the proper shipping name.
172.301
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Marking for Hazardous Materials with N.O.S. Proper Shipping Names
49 CFR 172.301
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MARKING AND LABELING III-5
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Technical Name Marking for Poison Inhalation Hazard Material
CFR 172.301
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This technical name marking requirement also applies to all shipping descriptions
for poisonous material. When the proper shipping name does not specifically
identify the poisonous material, add the technical name in parenthesis. 172.301(c)
| All Markings Must Be: |
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ALL markings must be durable, in English and printed on or affixed to the surface of
the package or on a label, tag or sign.
They must stand out. Place markings on a background of sharply contrasting color,
unobscured by labels or other matter.
Locate the required markings away from any other markings, such as advertising,
that could reduce the effectiveness of the HMR.
MARKING AND LABELING III-6
| Hazardous Substance |
|---|
|
For Hazardous Substances
Liquid, N.O.S. mark in
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A package of 119 gallons capacity or less containing a hazardous substance must
identify the hazardous substance by name in the proper shipping name.
If not, the package must bear one of the following descriptions:
1. the name of the hazardous substance as listed in the Appendix to the HMT;
2. if a waste stream, the waste stream number;
3. for wastes which exhibit an EPA characteristic of ignitability, corrosivity,
reactivity or toxicity, the letters "EPA" followed by "ignitability,"
"corrosivity," "reactivity" or "toxicity" or the corresponding "D" number, as
appropriate.
The appropriate description must be marked on the package in parenthesis in
association with the proper shipping name.
Note: Properly labeled radioactive material is excepted from this requirement.
172.324(a)(1)-(3)
MARKING AND LABELING III-7
| Hazardous Substance |
|---|
|
|
Each package that contains a hazardous substance must also be marked with the
letters "RQ." Place the "RQ" in association with the proper shipping name. It's not
necessary to mark the amount of the RQ on the package.
| Marine Pollutant |
|---|
|
49 CFR 172.322 |
MARINE POLLUTANTS 172.322
Bulk packages containing material classed as Marine Pollutants must be marked on
each end with the Marine Pollutant Mark in association with the hazard label or
shipping name if no label is required.
For transportation by vessel this requirement applies to non-bulk packages also.
MARKING AND LABELING III-8
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Elevated Temperature Material
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Bulk packages containing Elevated Temperature material must be marked on two
sides with the word "HOT". Molten Aluminum and Molten Sulfur must be marked
"MOLTEN ALUMINUM or MOLTEN SULFUR" as appropriate.
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Identification Number Marking
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Identification Number Marking
Non Bulk packages: A transport vehicle or freight container containing 4,000
kg(8,820lbs.) or more aggregate gross weight of a hazardous material having a
single identification number must be marked as required by Sections 172.326
through 172.338.
Bulk packages must be marked with the Identification Number either on orange
panels, placards, or white square on-point panels as required by Sections 172.326
through 172.338.
MARKING AND LABELING III-9

A transport vehicle or freight container containing 1,000 kg(2,205 lbs.) or more
aggregate gross weight of a hazardous material, poisonous by inhalation in Hazard
Zone A or B shall be marked with the identification number as required by Sections
172.313 and172.332
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Fumigant Marking
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No person may offer for transportation or transport a rail car, freight container, truck
body, or trailer in which the lading has been fumigated or treated with any material,
or is undergoing fumigation, unless the FUMIGANT Marking is prominently
displayed.
Additionally, for international shipments, transport documents must indicate the date
of fumigation, type and amount of fumigant used, and instructions for disposal of
any residual fumigant, including fumigation devices.
MARKING AND LABELING III-10
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The Term Label Means..
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The term "label," as used in the HMR, means a printed hazard warning notice.
Labels must be at least four inches by four inches. Labels are applied to the outside
of shipping containers of hazardous materials. Labels identify the primary and
secondary hazards specific to materials and may give information about handling
precautions and prohibitions. 172.407(b)
| Column 6, Label codes | |||
|---|---|---|---|
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(3)
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(4) | (5) | Label Codes |
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4.1 |
|||
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4.3
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|||
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6.1
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|||
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1.1A
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|||
Column 6 of the HMT contains a listing of the label codes which represent the
label(s) required for each hazardous material. The initial step in determining
appropriate labeling requirements is to check Column 6 of the HMT for any
required label(s).
172.101
MARKING AND LABELING III-11
| Column 6, Label codes | |||
|---|---|---|---|
|
(3)
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(4) | (5) | Label Codes |
|
4.1 |
|||
| 4.3 | |||
| 6.1 | |||
| None | |||
If Column 6 of the HMT says "none," then no label is required. Some sections of
the HMR provide exceptions to labeling requirements. In those cases, even though
the HMT specifies a label or label(s), labeling is not required.
172.101
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Before
Offering the Package..
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Unless otherwise provided, anyone offering for transportation a package, overpack
or freight container of hazardous material must label it, when required.
172.400(a)
MARKING AND LABELING III-12
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Prohibited
Labeling
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No person may offer and no carrier may transport a package of hazardous material
that displays markings or labels that could:
- be confused with or
- be in conflict with the label(s) prescribed by the HMR.
172.401(b)
The required label(s) must be printed on or affixed to the surface of the package
near the marked proper shipping name, unless exceptions are provided.
172.406(a)
MARKING AND LABELING III-13
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Label Placement
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The label may be printed on or affixed to a tag or by other suitable means when:
- the package contains no radioactive material and the label is larger than the
package;
- the package surface is such that a label cannot be affixed; and/or
- when the package is a compressed gas cylinder.
172.406(b)(1)-(3)
MARKING AND LABELING III-14

When labels are required, they must be:
- on a background of contrasting color or have a dotted or solid line outer
border and
- unobscured by markings or attachments.
When two or more labels are required, they must also be:
- displayed next to each other.
172.406(c)-(d),(f)
MARKING AND LABELING III-15
When required, two labels on at least two sides or ends, excluding the bottom, must
appear on:
- packages having a volume of 64 cubic feet or more,
- packages of radioactive material.
172.406(e)(1)-(2)
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Packages
64 cu ft or more
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A freight container having a volume of between 64 and 640 cubic feet:
- At least one label must be displayed on or near the closure for the freight
container. Placarding may not be used in place of labeling on a freight
container containing radioactive material.
172.406(e)(5)